P-H-FUNCTIONALIZED PHOSPHANIDO LIGANDS IN TRANSITION-METAL CHEMISTRY - MOLECULAR-STRUCTURE OF CPZR(MU-PH(T)BU)(2)(MU-P(T)BU)(2)(ZR(MU-CL)CP)(2)

Authors
FRENZEL C HEYHAWKINS E MULLER U STRENGER I
Citation
C. Frenzel et al., P-H-FUNCTIONALIZED PHOSPHANIDO LIGANDS IN TRANSITION-METAL CHEMISTRY - MOLECULAR-STRUCTURE OF CPZR(MU-PH(T)BU)(2)(MU-P(T)BU)(2)(ZR(MU-CL)CP)(2), Zeitschrift fur anorganische und allgemeine Chemie, 623(2), 1997, pp. 277-280
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
623
Issue
2
Year of publication
1997
Pages
277 - 280
Database
ISI
SICI code
0044-2313(1997)623:2<277:PPLITC>2.0.ZU;2-U
Abstract
The reaction of polymeric [CpZrCl(3)](n) with solvent-free LiPH(t)Bu y ields the trinuclear Zr-III/Zr-IV complex CpZr(mu-PH(t)Bu)(2)(mu-P(t)B u)(2)(Zr(mu-Cl)CP)(2) (1) in a redox reaction in low yield. The oxidat ion product (PH(t)Bu)(2) is observed by P-31-NMR spectroscopy. 1 cryst allises tetragonal in the space group P4(3)2(1)2 with a = 1130.5(5)pm and c = 3415.7(5) pm.