M. Maurus et al., METAL-COMPLEXES OF BIOLOGICALLY IMPORTANT LIGANDS .90. CHIRAL CYCLOPENTADIENYL-NITROSYL-MOLYBDENUM COMPLEXES OF ALPHA-AMINO CARBOXYLATES - (ETA(5)-C(5)R(5))(ON)(I)MO(ALPHA-AMINOCARBOXYLATE) (R=H, ME), Zeitschrift fur anorganische und allgemeine Chemie, 623(2), 1997, pp. 299-303
Citations number
29
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
The reactions of [(eta(5)-C5H5)Mo(NO)I-2](2) with glycinate, D-phenylg
lycinate, L-prolinate and L-azetidine-2-carboxylate give the chiral ch
elate complexes (eta(5)-C5H5)(ON)(I)Mo(alpha-aminocarboxylate) as mixt
ures of isomers. The x-ray diffraction of a crystal of (eta(5)-C(5)Me(
5))(ON)(I)MoNH2C(H)(tBu)CO2 shows trans configuration of the amino aci
d and nitrosyl donors in a tetragonal pyramid.