METAL-COMPLEXES OF BIOLOGICALLY IMPORTANT LIGANDS .90. CHIRAL CYCLOPENTADIENYL-NITROSYL-MOLYBDENUM COMPLEXES OF ALPHA-AMINO CARBOXYLATES - (ETA(5)-C(5)R(5))(ON)(I)MO(ALPHA-AMINOCARBOXYLATE) (R=H, ME)

Authors
MAURUS M AECHTER B HOFFMULLER W POLBORN K BECK W
Citation
M. Maurus et al., METAL-COMPLEXES OF BIOLOGICALLY IMPORTANT LIGANDS .90. CHIRAL CYCLOPENTADIENYL-NITROSYL-MOLYBDENUM COMPLEXES OF ALPHA-AMINO CARBOXYLATES - (ETA(5)-C(5)R(5))(ON)(I)MO(ALPHA-AMINOCARBOXYLATE) (R=H, ME), Zeitschrift fur anorganische und allgemeine Chemie, 623(2), 1997, pp. 299-303
Citations number
29
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
623
Issue
2
Year of publication
1997
Pages
299 - 303
Database
ISI
SICI code
0044-2313(1997)623:2<299:MOBIL.>2.0.ZU;2-B
Abstract
The reactions of [(eta(5)-C5H5)Mo(NO)I-2](2) with glycinate, D-phenylg lycinate, L-prolinate and L-azetidine-2-carboxylate give the chiral ch elate complexes (eta(5)-C5H5)(ON)(I)Mo(alpha-aminocarboxylate) as mixt ures of isomers. The x-ray diffraction of a crystal of (eta(5)-C(5)Me( 5))(ON)(I)MoNH2C(H)(tBu)CO2 shows trans configuration of the amino aci d and nitrosyl donors in a tetragonal pyramid.