H. Wood et al., THE EFFECT OF POLYETHERSULFONE CONCENTRATION ON FLAT AND HOLLOW-FIBERMEMBRANE PERFORMANCE, Separation science and technology, 28(15-16), 1993, pp. 2297-2317
Flat and hollow fiber (HF) membranes are made in order to determine th
e effect of the polyethersulfone (PES) concentration in the precursor
film-casting solution on resultant flat and hollow fiber membrane perf
ormance. The additive polyvinyl-pyrrolidone (PVP) is included in the f
ilm-casting solution to ensure that membranes can be made over wide va
riations in the PES polymer concentration. In general, membrane permea
bility decreases and solute separation ability increases as the PES co
ncentration increases. However, for both flat and HF membranes, perfor
mance is strongly dependent on whether the PES concentration is above
or below the critical value. Flux greatly decreases and solute-separat
ion ability increases when the critical PES concentration is surpassed
. Membrane performance is generally optimized when the PES concentrati
on is at the critical value.