SPECTROSCOPIC INVESTIGATION OF A GELLING AGENT INCLUDED IN POLY(DIMETHYLSILOXANE) GELS

Citation
T. Itoh et al., SPECTROSCOPIC INVESTIGATION OF A GELLING AGENT INCLUDED IN POLY(DIMETHYLSILOXANE) GELS, Journal of materials chemistry, 3(12), 1993, pp. 1303-1305
Citations number
6
Categorie Soggetti
Chemistry Physical","Material Science
ISSN journal
09599428
Volume
3
Issue
12
Year of publication
1993
Pages
1303 - 1305
Database
ISI
SICI code
0959-9428(1993)3:12<1303:SIOAGA>2.0.ZU;2-1
Abstract
Poly(dimethylsiloxane) gels containing different amounts of cholestery l anthraquinone-2-carboxylate (CAQ), used as a gelling agent, have bee n prepared and the phosphorescence spectra of CAQ contained in the gel s were measured at 77 K. Two forms of CAQ, free and crystalline, were identified through the phosphorescence measurements, and the relative amounts were determined. It is shown that the relative amount of cryst alline CAQ in the gel decreases with decreasing bulk CAQ content.