K. Yamamoto et al., INFLUENCE OF SUPERCOOLING OF HEAT SUPPORT HYDROGEL ON THE EFFICIENCY OF ICE STORAGE BY EVACUATION AND A METHOD FOR BRAKING THE SUPERCOOLING, Kagaku kogaku ronbunshu, 19(6), 1993, pp. 1023-1030
The proposed ice storage system uses several kinds of hydrogel as heat
supports. The vaporization heat of water from highly water-containing
gel is stored as the heat of freezing of the remaining water. The fir
st key to the realization of this system is development of a vacuum co
mpressor with large evacuation rate for water vapor at low pressure an
d with high efficiency. It is also important to evaporate water at hig
h temperature, as near the freezing point as possible, to produce ice
with high efficiency. A 1-liter cylindrical Dewar vessel made of stain
less steel was used as a heat container and diaphragm pumps were used
for evacuation. Four types of polymer gel materials and two kinds of i
ce nucleation active substances (INS), AgI and ice nucleation active p
rotein (INAP) produced by an ice nucleation active bacterium (INB: Xan
tmonas campestris), were used in the experiments. For practical use, t
he evaporation rate of water is described as proportional to the vapor
pressure of water at the temperature of the gel. Both kinds of INS we
re effective in raising,the break-point of supercooling from -5 approx
imately -8-degrees-C (without INS) to -1 approximately -3-degrees-C (w
ith INS). INAP is recommended for use in this system as a harmless, re
producible organic INS.