DIMERIZATION OF THE STELLATED OCTAHEDRAL UNIT CO6S8P6 - SYNTHESIS ANDX-RAY CRYSTAL-STRUCTURE OF [CO12(MU-3-S)14(MU-4-S)2(PET3)10][TCNQ]2, WHERE TCNQ = TETRACYANOQUINODIMETHANE

Authors
CECCONI F GHILARDI CA MIDOLLINI S ORLANDINI A
Citation
F. Cecconi et al., DIMERIZATION OF THE STELLATED OCTAHEDRAL UNIT CO6S8P6 - SYNTHESIS ANDX-RAY CRYSTAL-STRUCTURE OF [CO12(MU-3-S)14(MU-4-S)2(PET3)10][TCNQ]2, WHERE TCNQ = TETRACYANOQUINODIMETHANE, Inorganica Chimica Acta, 214(1-2), 1993, pp. 13-15
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
214
Issue
1-2
Year of publication
1993
Pages
13 - 15
Database
ISI
SICI code
0020-1693(1993)214:1-2<13:DOTSOU>2.0.ZU;2-#
Abstract
The unprecedented double stellated octahedral cluster [Co12(mu3-S)14(m u4-S)2(PEt3)10][TCNQ]2, has been isolated and characterized by an X-ra y structure determination. The cation contains two stellated octahedra l Co6S8 cores linked together through two mu4-S bridging ligands. The tetracyanoquinodimethane anion exists as the [TCNQ]22- diner, exhibiti ng the ring-over exocyclic bond type overlap.