APPENDING 2 NONEQUIVALENT FERROCENE FRAGMENTS TO A METALLOCYCLAM CORE

Authors
DESANTIS G FABBRIZZI L LICCHELLI M MANGANO C PALLAVICINI P
Citation
G. Desantis et al., APPENDING 2 NONEQUIVALENT FERROCENE FRAGMENTS TO A METALLOCYCLAM CORE, Inorganica Chimica Acta, 214(1-2), 1993, pp. 193-196
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
214
Issue
1-2
Year of publication
1993
Pages
193 - 196
Database
ISI
SICI code
0020-1693(1993)214:1-2<193:A2NFFT>2.0.ZU;2-F
Abstract
A three-component system in which two non-equivalent ferrocene fragmen ts are appended to a metallocyclam subunit has been prepared through a n Ni(II) template synthesis. The system undergoes two distinct and con secutive reversible one-electron oxidation processes centred on the tw o ferrocene fragments, but decomposes on oxidation of the Ni(II) centr e.