HIGHLY EFFECTIVE PQQ INHIBITION BY ALKYNYL AND ARYL MONOIODONIUM AND DIIODONIUM SALTS

Authors
GALLOP PM PAZ MA FLUCKIGER R STANG PJ ZHDANKIN VV TYKWINSKI RR
Citation
Pm. Gallop et al., HIGHLY EFFECTIVE PQQ INHIBITION BY ALKYNYL AND ARYL MONOIODONIUM AND DIIODONIUM SALTS, Journal of the American Chemical Society, 115(25), 1993, pp. 11702-11704
Citations number
44
Categorie Soggetti
Chemistry
Journal title
Journal of the American Chemical Society → ACNP
ISSN journal
00027863
Volume
115
Issue
25
Year of publication
1993
Pages
11702 - 11704
Database
ISI
SICI code
0002-7863(1993)115:25<11702:HEPIBA>2.0.ZU;2-Z
Abstract
PQQ (methoxatin), a bis(quinone) tricarboxylic acid, is an organic cof actor in a variety of biological redox processes. It is effectively in hibited on a micromolar scale by alkynyl and aryl monoiodonium salts, whereas bis(iodonium)triflates 5 and 8 are PQQ inhibitors at nanomolar levels.