A nonmechanical approach to the construction of complex three-dimensio
nal interconnect arrays has been developed with the use of conducting
polymer dendrites. Electrically independent connections between pairs
of wires in an array were successfully grown through alternating-curre
nt electrochemical polymerization of poly(3-methylthiophene), without
mechanical or optical masking steps. The electrically active links wer
e insulated by subsequent electropolymerization of 4-vinylpyridine or
2-methylthiophene or by the dip-coating of the connections in a polyst
yrene solution.