REACTIONS OF PALLADIUM(IV), BIS(DIPHENYLPHOSPHINO)METHANE (DPPM), ANDNABH4 IN THE PRESENCE OF CO STRUCTURE OF PD6(MU-2-CO)6(MU-DPPM)3

Authors
HOLAH DG HUGHES AN KRYSA E MAGNUSON VR
Citation
Dg. Holah et al., REACTIONS OF PALLADIUM(IV), BIS(DIPHENYLPHOSPHINO)METHANE (DPPM), ANDNABH4 IN THE PRESENCE OF CO STRUCTURE OF PD6(MU-2-CO)6(MU-DPPM)3, Organometallics, 12(12), 1993, pp. 4721-4722
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
12
Issue
12
Year of publication
1993
Pages
4721 - 4722
Database
ISI
SICI code
0276-7333(1993)12:12<4721:ROPB(A>2.0.ZU;2-M
Abstract
The synthesis and structural characterization of the title compound ar e reported. It is a new type of palladium(0) hexamer consisting of two almost planar Pd3(mu2-CO)3P3 units bridged by the -CH2- groups of the three dppm ligands in such a way that the two almost planar Pd3 units are only approximately 10-degrees from being eclipsed.