5-PENTAKIS(PROPYN-1-YL)CYCLOPENTADIENYL]-MANGANESE

Authors
BUNZ UHF ENKELMANN V RADER J
Citation
Uhf. Bunz et al., 5-PENTAKIS(PROPYN-1-YL)CYCLOPENTADIENYL]-MANGANESE, Organometallics, 12(12), 1993, pp. 4745-4747
Citations number
30
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
12
Issue
12
Year of publication
1993
Pages
4745 - 4747
Database
ISI
SICI code
0276-7333(1993)12:12<4745:5>2.0.ZU;2-4
Abstract
The title compound ,5-pentakis(propyn-1-yl)cyclopentadienyl]manganese (1b) was prepared in two steps from tricarbonylcyclopentadienylmangane se. The key step involves a 5-fold Stille coupling of eta5-1,2,3,4,5-p entaiodocyclopentadienyl)manganese with 1-(trimethylstannyl)prop-1-yne .