DEHYDROGENATIVE SILYLATION OF 1,5-DIENES WITH HYDROSILANES CATALYZED BY RHCL(PPH3)3

Authors
KAKIUCHI F NOGAMI K CHATANI N SEKI Y MURAI S
Citation
F. Kakiuchi et al., DEHYDROGENATIVE SILYLATION OF 1,5-DIENES WITH HYDROSILANES CATALYZED BY RHCL(PPH3)3, Organometallics, 12(12), 1993, pp. 4748-4750
Citations number
39
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
12
Issue
12
Year of publication
1993
Pages
4748 - 4750
Database
ISI
SICI code
0276-7333(1993)12:12<4748:DSO1WH>2.0.ZU;2-P
Abstract
The reaction of 1,5-dienes with hydrosilanes using RhCl(PPh3)3 as a ca talyst gives 1-silyl-1,5-dienes as the result of dehydrogenative silyl ation instead of the usual hydrosilylation products.