CATALYTIC TRANSFER HYDROGENATION OF BENZALDEHYDE IN A MICROWAVE-OVEN

Citation
Em. Gordon et al., CATALYTIC TRANSFER HYDROGENATION OF BENZALDEHYDE IN A MICROWAVE-OVEN, Organometallics, 12(12), 1993, pp. 5020-5022
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
ISSN journal
02767333
Volume
12
Issue
12
Year of publication
1993
Pages
5020 - 5022
Database
ISI
SICI code
0276-7333(1993)12:12<5020:CTHOBI>2.0.ZU;2-Y
Abstract
The catalytic transfer hydrogenation of benzaldehyde catalyzed by hlor ohydridotris-(triphenylphosphine)ruthenium(II) was carried out in a se aled Teflon vessel using a household microwave oven as the heat source . Carrying out the reaction in the microwave oven produced an improvem ent in the average catalytic turnover rate from 280 to 6700 turnovers/ h in comparison with traditional reflux heating.