SYNTHESIS AND CRYSTAL-STRUCTURE OF TETRAHYDROFURFURYLCYCLOPENTADIENYLSODIUM TETRAHYDROFURANATE COMPLEX

Authors
ZHANG SB LIU JZ WEI GC LIN GY CHEN WQ
Citation
Sb. Zhang et al., SYNTHESIS AND CRYSTAL-STRUCTURE OF TETRAHYDROFURFURYLCYCLOPENTADIENYLSODIUM TETRAHYDROFURANATE COMPLEX, Polyhedron, 12(23), 1993, pp. 2771-2774
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
12
Issue
23
Year of publication
1993
Pages
2771 - 2774
Database
ISI
SICI code
0277-5387(1993)12:23<2771:SACOT>2.0.ZU;2-S
Abstract
A tetrahydrofurfurylcyclopentadienyl sodium tetrahydrofuranate complex was prepared by the reaction of tetrahydrofurfurylcyclopentadiene wit h metallic sodium in THF. Its crystal structure was determined by X-ra y analysis. In the crystal. the tetrahydrofuranate complex C4H7OCH2C5H 4Na . THF adopts a puckered chain structure with an eta5-(C4H7OCH2)C5H 4 ring connected by a bridging Na(THF) unit. The oxygen in the eta5-(C 4H7OCH2)C5H4 ring is coordinated to the sodium atom.