MOLECULAR-STRUCTURE AND CHARGE-DISTRIBUTION IN COMPOUNDS OF THE 5F-ELEMENTS .6. 1 1 ADDUCTS OF ROTRIS(3,5-DIMETHYLPYRAZOL-1-YL)BORATE-TRICHLORIDE WITH LEWIS-BASES/

Authors
MAIER R MULLER J KANELLAKOPULOS B APOSTOLIDIS C DOMINGOS A MARQUES N DEMATOS AP
Citation
R. Maier et al., MOLECULAR-STRUCTURE AND CHARGE-DISTRIBUTION IN COMPOUNDS OF THE 5F-ELEMENTS .6. 1 1 ADDUCTS OF ROTRIS(3,5-DIMETHYLPYRAZOL-1-YL)BORATE-TRICHLORIDE WITH LEWIS-BASES/, Polyhedron, 12(23), 1993, pp. 2801-2808
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
12
Issue
23
Year of publication
1993
Pages
2801 - 2808
Database
ISI
SICI code
0277-5387(1993)12:23<2801:MACICO>2.0.ZU;2-Y
Abstract
The 1:1 adducts Of UCl3[HB(3,5-Me2Pz)3] with thf. pyridine (NC5H5), ac etonitrile (MeCN), benzonitrile (PhCN), cyclohexylisocyanide (C6H12NC) , triethylphosphate (tep), tributylphosphate (tbp) and triphenylphosph ine oxide (tppo) have been prepared and characterized. The structure o f the tep compound was determined by single-crystal X-ray analysis. Th e charge distribution within the molecules was determined and its corr elation with spectroscopic data is discussed. The relative affinity of the Lewis base to the uranium central ion was determined by base exch ange reactions and found to be tppo > RNC > RCN > tep > tbp > NC5H5 > thf.