TRANSITION-METAL COMPLEXES OF DIALKYL ALPHA-HYDROXYIMINOPHOSPHONATES,A NOVEL CLASS OF METAL-COMPLEXES

Authors
BLIGH SWA CHOI N GREEN DSC HUDSON HR MCGRATH CM MCPARTLIN M PIANKA M
Citation
Swa. Bligh et al., TRANSITION-METAL COMPLEXES OF DIALKYL ALPHA-HYDROXYIMINOPHOSPHONATES,A NOVEL CLASS OF METAL-COMPLEXES, Polyhedron, 12(23), 1993, pp. 2887-2890
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
12
Issue
23
Year of publication
1993
Pages
2887 - 2890
Database
ISI
SICI code
0277-5387(1993)12:23<2887:TCODA>2.0.ZU;2-X
Abstract
A new range of dialkyl alpha-hydroxyiminophosphonates has been prepare d and the first examples of metal complexes of this class of compound have been obtained; X-rav crystal structure analysis of the dichlorobi s(diethyl -(alpha)-hydroxyiminopropanephosphonate)nickel(II) complex s hows a distorted octahedral coordination at the nickel atom giving two symmetry related diethyl-(E)-alpha-hydroxyiminopropanephosphonate lig ands and two chlorine donors.