J. Goworek et W. Stefaniak, THE INVESTIGATION OF THE PORE STRUCTURE OF SILICA-GELS WITH LONG-CHAIN ALKYL GRAFTS BY THERMAL-ANALYSIS, Colloids and surfaces. A, Physicochemical and engineering aspects, 80(2-3), 1993, pp. 251-256
The total pore volumes and the core size distributions were calculated
for the silica gel Si-100 and chemically modified silica gels RP-8 an
d RP-18 on the basis of the thermal desorption data of various liquids
. The results obtained are compared with those from the nitrogen adsor
ption/desorption method. Good consistency between the parameters obtai
ned by using different methods is observed in the case of unmodified s
ilica gel. The presence of long alkyl chains on the silica surface str
ongly influences the pore diameter calculated from thermogravimetric d
ata.