Wh. Jo et al., SEPARATION OF WATER-ETHANOL MIXTURE THROUGH POLY(ACRYLONITRILE-CO-ACRYLIC ACID) POLY(ETHYLENE OXIDE) MEMBRANES BY PERVAPORATION, Journal of applied polymer science, 51(3), 1994, pp. 529-535
The separation of water/ethanol mixtures was investigated by poly(acry
lonitrile-co-acrylic acid) and by poly(acrylonitrile-co-acrylic acid)/
poly(ethylene oxide) blend membranes. The flux increased with the cont
ent of acrylic acid in copolymers and the selectivity remained constan
t. The marked increase of the selectivity was observed for blend membr
anes of a certain blend ratio, suggesting that the two polymers are pa
rtially miscible. Poly (ethylene oxide) in blends was thought to act a
s a plasticizer as well as a preferentially water absorbing and diffus
ing component. (C) 1994 John Wiley & Sons, Inc.