THE MECHANISM OF OXIDATION OF ANILINE BY PEROXY-COMPOUNDS - CAN EPR SPECTROSCOPY HELP TO DISCRIMINATE BETWEEN ONE-ELECTRON TRANSFER AND A NUCLEOPHILIC-SUBSTITUTION PROCESS

Authors
GROSSI L
Citation
L. Grossi, THE MECHANISM OF OXIDATION OF ANILINE BY PEROXY-COMPOUNDS - CAN EPR SPECTROSCOPY HELP TO DISCRIMINATE BETWEEN ONE-ELECTRON TRANSFER AND A NUCLEOPHILIC-SUBSTITUTION PROCESS, Research of chemical intermediates, 19(8), 1993, pp. 697-705
Citations number
19
Categorie Soggetti
Chemistry
Journal title
Research of chemical intermediates → ACNP
ISSN journal
09226168
Volume
19
Issue
8
Year of publication
1993
Pages
697 - 705
Database
ISI
SICI code
0922-6168(1993)19:8<697:TMOOOA>2.0.ZU;2-4
Abstract
Aniline reacts with several organic peroxy compounds at room temperatu re to yield radical intermediates detectable by E.P.R.. The reaction o f these oxidants with aniline has been studied in detail and the radic al species identified lead to the support of a one-electron transfer p rocess preferentially to an S-N mechanism.