EPR AND ENDOR OF FREE-RADICALS FORMED DURING THE AEROBIC OXIDATION OFCHLOROGENIC ACID AND OF CAFFEIC ACID IN STRONGLY ALKALINE-SOLUTION

Authors
ATHERTON NM WILLDER JSS
Citation
Nm. Atherton et Jss. Willder, EPR AND ENDOR OF FREE-RADICALS FORMED DURING THE AEROBIC OXIDATION OFCHLOROGENIC ACID AND OF CAFFEIC ACID IN STRONGLY ALKALINE-SOLUTION, Research of chemical intermediates, 19(8), 1993, pp. 787-795
Citations number
9
Categorie Soggetti
Chemistry
Journal title
Research of chemical intermediates → ACNP
ISSN journal
09226168
Volume
19
Issue
8
Year of publication
1993
Pages
787 - 795
Database
ISI
SICI code
0922-6168(1993)19:8<787:EAEOFF>2.0.ZU;2-O
Abstract
The proton hyperfine coupling constants in three free radicals which a re formed during the aerobic oxidation of either chlorogenic acid or o f caffeic acid in strongly alkaline solution have been measured using EPR and ENDOR spectroscopy and the three radicals thus characterised. Possible identities for the free radicals are discussed.