Air-sea exchange represents an important controlling factor for the di
stribution of carbon isotopes in the modern ocean, even below the surf
ace mixed layer. Here we show that this thermodynamic influence varies
between water masses with a magnitude which is large relative to the
amplitude of typical deep sea sediment delta(13)C records. Thus, chang
es in air-sea exchange processes must be regarded as a significant sou
rce of variability for any marine delta(13)C signal.