THE SYNTHESIS OF BIS(BENZO-15-CROWN-5) DERIVATIVES AND THEIR USE IN POTASSIUM PVC MEMBRANE ELECTRODES

Citation
Ag. Li et al., THE SYNTHESIS OF BIS(BENZO-15-CROWN-5) DERIVATIVES AND THEIR USE IN POTASSIUM PVC MEMBRANE ELECTRODES, Journal of inclusion phenomena and molecular recognition in chemistry, 15(4), 1993, pp. 317-327
Citations number
22
Categorie Soggetti
Chemistry,Crystallography
ISSN journal
09230750
Volume
15
Issue
4
Year of publication
1993
Pages
317 - 327
Database
ISI
SICI code
0923-0750(1993)15:4<317:TSOBDA>2.0.ZU;2-H
Abstract
Five new bis(benzo-15-crown-5) derivatives with different connecting g roups were synthesized. Potassium ion-selective PVC membrane electrode s based on these bis(crown ether)s were prepared and their selective p roperties were measured. The results showed that most of these electro des are stable over a wide pH range and their selectivity coefficients were better than those of an electrode based on natural valinomycin.