Organic electrophotographic receptors have been enabled by the develop
ment of unique classes of high dielectric strength glassy polymer coat
ings, which, though insulating, are nevertheless capable of transporti
ng injected charge with relatively high mobility and negligible loss t
o deep traps. Key features of electronic transport in these materials
and the underlying physics are described. Additionally, it is demonstr
ated that these trap-free transport polymers provide a unique venue fo
r the exploration of contact behavior and the factors controlling inje
ction efficiency In disordered organic solids.