FACILE CLEAVAGE OF CARBON-PALLADIUM BONDS IN C60PDN WITH PHOSPHINES AND PHOSPHITES - AN ALTERNATIVE ROUTE TO (ETA-2-C60)PDL2 AND DISCOVERY OF FLUXIONARITY SUGGESTING THE ROTATION OF C-60 ON THE PDL2 SPECIES INSOLUTION

Authors
NAGASHIMA H YAMAGUCHI H KATO Y SAITO Y HAGA MA ITOH KJ
Citation
H. Nagashima et al., FACILE CLEAVAGE OF CARBON-PALLADIUM BONDS IN C60PDN WITH PHOSPHINES AND PHOSPHITES - AN ALTERNATIVE ROUTE TO (ETA-2-C60)PDL2 AND DISCOVERY OF FLUXIONARITY SUGGESTING THE ROTATION OF C-60 ON THE PDL2 SPECIES INSOLUTION, Chemistry Letters, (12), 1993, pp. 2153-2156
Citations number
18
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
12
Year of publication
1993
Pages
2153 - 2156
Database
ISI
SICI code
0366-7022(1993):12<2153:FCOCBI>2.0.ZU;2-6
Abstract
Carbon-palladium bonds in C60Pdn are easily cleaved with phosphines an d phosphites to afford C60[PdL2]n. The reaction with C60Pdn (n = 1.0-1 .4) offers an alternative synthetic route to C60PdL2. Fluxional behavi or indicating rotation of C60 on the PdL2 species in solution is obser ved on C-13 NMR spectra of C60PdL2, where L = PMe2Ph, PPh2Me, and P(OM e)3.