Db. Buchholz et al., SURFACE-MORPHOLOGY STUDIES OF Y-BA-CU-OXIDE THIN-FILMS PREPARED BY PULSED ORGANOMETALLIC BEAM EPITAXY, Materials chemistry and physics, 36(3-4), 1994, pp. 377-382
Pulsed organometallic beam epitaxy is a new technique for the depositi
on of complex metal oxide films. With this technique each metal precur
sor species is sequentially pulsed onto the substrate. The flux of the
precursor is monitored and computer feedback control is used to adjus
t the size of each precursor pulse, allowing precise control of the me
tal stoichiometry. Smooth films of YBa2CU3O7-delta, as examined by SEM
, can be made with this technique in a temperature range that includes
640-680-degrees-C using the beta-diketonate precursors, Y(dipivalolym
ethanate)3, Ba(hexafluoroacetylacetonate)2.tetraglyme, and Cu(acetylac
etonate)2. The morphology of the films is dependent on the ratio of th
e three precursors delivered to the substrate. The ratio of the three
precursors must be held to better than +/-10% in order to produce smoo
th films. The ratio between the three precursors needed to produce a s
mooth film changes with the deposition temperature. The relative amoun
t of yttrium precursor delivered to the substrate must be decreased as
the temperature is increased in order to maintain a smooth film. The
metal composition of the smooth films is Y1Ba2CU3 (+/-4%).