INVERSION OF CONFIGURATION OF ALPHA-TRISUBSTITUTED (NEOPENTYL) TYPE SECONDARY ALCOHOLS

Authors
MORIARTY RM ZHUANG H PENMASTA R LIU K AWASTHI AK TULADHAR SM RAO MSC SINGH VK
Citation
Rm. Moriarty et al., INVERSION OF CONFIGURATION OF ALPHA-TRISUBSTITUTED (NEOPENTYL) TYPE SECONDARY ALCOHOLS, Tetrahedron letters, 34(50), 1993, pp. 8029-8032
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
34
Issue
50
Year of publication
1993
Pages
8029 - 8032
Database
ISI
SICI code
0040-4039(1993)34:50<8029:IOCOA(>2.0.ZU;2-4
Abstract
A variety of hindered alpha-trisubstituted optically active secondary alcohols has been converted into their enantiomers by treating the cor responding triflates with KNO2 in DMF in the presence of 18-crown-6 at room temperature.