PHOTOCHEMICAL RING-OPENING OF CYCLOPROPYL KETONES INDUCED BY ELECTRON-TRANSFER

Authors
COSSY J FURET N
Citation
J. Cossy et N. Furet, PHOTOCHEMICAL RING-OPENING OF CYCLOPROPYL KETONES INDUCED BY ELECTRON-TRANSFER, Tetrahedron letters, 34(50), 1993, pp. 8107-8110
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
34
Issue
50
Year of publication
1993
Pages
8107 - 8110
Database
ISI
SICI code
0040-4039(1993)34:50<8107:PROCKI>2.0.ZU;2-Q
Abstract
Irradiation of substituted bicyclo[n.1.0.]alkan-2-ones at 254 nm in th e presence of triethylamine and lithium perchlorate (LIClO(4)) can lea d to cyclopropane ring opening with cleavage of the C(1)-C(n+2) (ring enlargement) or C(1)-C(n+3) bonds.