STEREOCHEMISTRY OF THE CONVERSION OF (R) CORIOLIC ACID INTO DELTA-DECANOLIDE IN CLADOSPORIUM-SUAVEOLENS

Authors
FRONZA G FUGANTI C GRASSELLI P ZUCCHI G ALLEGRONE G BARBENI M CABELLA P CISERO M
Citation
G. Fronza et al., STEREOCHEMISTRY OF THE CONVERSION OF (R) CORIOLIC ACID INTO DELTA-DECANOLIDE IN CLADOSPORIUM-SUAVEOLENS, Biotechnology letters, 15(12), 1993, pp. 1233-1236
Citations number
10
Categorie Soggetti
Biothechnology & Applied Migrobiology
Journal title
Biotechnology letters → ACNP
ISSN journal
01415492
Volume
15
Issue
12
Year of publication
1993
Pages
1233 - 1236
Database
ISI
SICI code
0141-5492(1993)15:12<1233:SOTCO(>2.0.ZU;2-0
Abstract
In growing cultures of Cladosporium suaveolens (R) coriolic acid (3) i s converted into delta-decanolide enriched in the (S) enantiomer (2) ( ca. 0.4 ee), while recovered coriolic acid shows the same enantiomeric composition of the precursor, as indicated by NMR studies onto a set of (+)-MTPA derivatives.