REACTION OF PENTACARBONYL(METHYLPYRROLIDINOCARBENE)CHROMIUM(0) WITH ALDEHYDES - A NEW ENTRY TO ENTACARBONYL(ALKENYLPYRROLIDINOCARBENE)CHROMIUM(0)

Authors
BALDOLI C DELBUTTERO P LICANDRO E MAIORANA S PAPAGNI A ZANOTTIGEROSA A
Citation
C. Baldoli et al., REACTION OF PENTACARBONYL(METHYLPYRROLIDINOCARBENE)CHROMIUM(0) WITH ALDEHYDES - A NEW ENTRY TO ENTACARBONYL(ALKENYLPYRROLIDINOCARBENE)CHROMIUM(0), Synlett, (12), 1993, pp. 935-936
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
12
Year of publication
1993
Pages
935 - 936
Database
ISI
SICI code
0936-5214(1993):12<935:ROPWA>2.0.ZU;2-J
Abstract
The conjugate base of pentacarbonyl(methylpyrrolidinocarbene)chromium( 0) (1) easily reacts with aldehydes, yielding aldol products (2). The latter are converted into the corresponding pentacarbonyl(alkenylpyrro lidinocarbene) complexes with high E selection under very mild conditi ons.