A NOVEL TRICYCLE WITH A PLANAR TETRAGERMANIUM(I) 4-MEMBERED RING

Authors
KARSCH HH BAUMGARTNER G GAMPER S
Citation
Hh. Karsch et al., A NOVEL TRICYCLE WITH A PLANAR TETRAGERMANIUM(I) 4-MEMBERED RING, Journal of organometallic chemistry, 462(1-2), 1993, pp. 30000003-30000005
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
462
Issue
1-2
Year of publication
1993
Pages
30000003 - 30000005
Database
ISI
SICI code
0022-328X(1993)462:1-2<30000003:ANTWAP>2.0.ZU;2-D
Abstract
Nucleophilic attack of Li(t)Bu on Ge-2[C(PMe(2))(2)(SiMe(3))](2) leads , via formation of {Li[C(PMe(2))(2)(SiMe(3))]}(2), to the novel tricyc le Ge-4 [C(PMe(2))(2)(SiMe(3))](2)((t)Bu)(2), which contains a planar four-membered ring of Ge-I atoms. The compound was characterized by me ans of NMR spectroscopy and an X-ray diffraction study.