FINE-STRUCTURE BRANCHING RATIOS AND TRANSLATIONAL ENERGIES OF O(P-3(J)) ATOMS PRODUCED FROM COLLISION-INDUCED INTERSYSTEM CROSSING OF O(1D)ATOMS

Collision induced intersystem crossing of O (2p 1D) to 0 (2p P-3(j)) j = 0,1,2 was studied by vacuum-ultraviolet laser induced fluorescence. The nascent j-branching ratios of O(P-3(j)) produced from collision o f O(1D) with Xe, Kr, N2, CO2, and CF3H at the collision energy of 15.6 , 14.7, 11.4, 13.0, and 14.4 kcal/mol are 3(0))]/[O(P-3(1))]/[O(P-3(2) )]=(0.28+/-0.04)/(0.58 +/-0.05)/1, (0.33+/-0.05)/(0.45+/-0.07)/1, (0.2 3+/-0.05)/(0.35+/-0.05)/1, (0.14+/-0.05)/(0.41 +/-0.05)/1, and (0.20+/ -0.05)/(0.45+/-0.05)/1, respectively. The j-branching ratios are discu ssed in terms of potential curve crossing between singlet and triplet surfaces and nonadiabatic nature of the potential surfaces. Doppler pr ofiles of the product O(P-3(j)) atoms were measured as a function of t ime delay between pump and probe laser pulses. By calculating the kine tic energy from the Doppler profiles, electronic energy transfer effic iencies to the internal energy of N2, CO, CO2, and CF3H are obtained t o be (30+/-7), (31+/-7), (49+/-3), and (52+/-5) %, respectively.