ZnCH3 and CdCH3 radicals have been prepared in a cold supersonic free
jet expansion and their laser-induced-fluorescence spectrum recorded f
or the A 2E <-- X 2A1 electronic transition. These spectra show well r
esolved rotational and spin structure, which has been completely analy
zed. This analysis yields the rotational constants and the components
of the spin-rotation tensors in the A and X states of both radicals. T
he observed constants are discussed in terms of the electronic structu
re of the radicals. It is demonstrated that the upper F2 spin-orbit co
mponent of the A 2E state of CdCH3 is strongly perturbed by another, d
issociative electronic state. This leads to some predissociation of th
e A 2E3/2 Component and a broadening of its lines. The rotational and
fine structure in this state is also quite perturbed leading to an unu
sual, but still interpretable spectrum.