Using a thin predeposited B layer prior to the epitaxial growth of Ge
on CaF2, we have obtained significantly improved Ge crystalline qualit
y and surface morphology for Ge/CaF2/Si(111) and Ge/CaF2/Si(100) StruC
tUres. Although B acts as a surfactant in suppressing island formation
, it does not migrate to the growth front during Ge growth, which was
widely observed in the surfactant-assisted epitaxial growth of Ge on S
i. The B predeposit also prevents Ca from migrating to the Ge surface,
and promotes A-type epitaxy of Ge (111) when Si (111) substrates are
used.