B. Chantegrel et al., REACTION OF TRIFLUOROACETIC-ANHYDRIDE WITH N-(2-HYDROXYBENZYL)-ALPHA-AMINO ACIDS - AN ENTRY IN THE NEW [1,3]OXAZOLO[2,3-B][1,3]BENZOXAZINE RING-SYSTEM, Heterocycles, 36(12), 1993, pp. 2811-2818
The diastereospecific double ring closure of N-(2-hydroxybenzyl)-alpha
-amino acids with trifluoroacetic anhydride leads to the formation of
dro-[1,3]oxazolo[2,3-b][1,3]benzoxazin-2(5H)-ones. The chemical struct
ures are supported by ir, H-1-nmr and C-13-nmr spectra and X-ray analy
sis.