Hc. Shih et al., APPLICATION OF NICKEL-PLATING FOR THE SYNTHESIS OF CHEMICAL-VAPOR-DEPOSITION OF DIAMOND ON STEELS, Thin solid films, 236(1-2), 1993, pp. 111-114
The major problem with wear-resistant diamond coatings in applications
is the poor adhesion. The application of a buffer material holds some
promise and has shown some successes. In this study, a commercially a
vailable process of electroless nickel plating was applied to steel as
an intermediate layer for diamond chemical vapour depositions, by rea
son of the buffering material being softer than diamond and the stress
relaxing, with increasing nickel thickness. Both continuous diamond f
ilm on a nickel plate and discrete diamond particles embedded in a nic
kel matrix were formed in a microwave plasma-assisted chemical vapour
deposition system. The results of tribotesting indicated that the cont
inuous diamond film as top coating usually suffers from the microcrack
s, while the composite-like coating improves the wear resistance signi
ficantly, though at the expense of losing some surface hardness in com
parison with that of the pure diamond coating.