Experimental evidence suggests that under certain circumstances the se
lectivity (or classification) function for hydrocyclones does not alwa
ys conform the expected 'S' shape but exhibits a dip in regions of the
finer particle sizes (typically less than 20 mu m). This dip is known
as the 'fish-hook effect' and is of considerable industrial significa
nce because it mediates the classification efficiency of ultra-fine ma
terials. Only two previous attempts have been carried out to model the
effect and, moreover, the existence of the phenomenon itself has been
disputed. This paper presents a critical assessment of previous work
and new evidence for its existence based on in situ particle size meas
urements on the process streams coupled with robust data reconciliatio
n procedures. A theory to account for the phenomenon and a new empiric
al model are proposed and tested.