PALLADIUM AND PHASE-TRANSFER-CATALYZED CARBONYLATION OF PROPARGYL DERIVATIVES

Citation
H. Arzoumanian et al., PALLADIUM AND PHASE-TRANSFER-CATALYZED CARBONYLATION OF PROPARGYL DERIVATIVES, Journal of molecular catalysis, 85(3), 1993, pp. 287-293
Citations number
26
Categorie Soggetti
Chemistry Physical
ISSN journal
03045102
Volume
85
Issue
3
Year of publication
1993
Pages
287 - 293
Database
ISI
SICI code
0304-5102(1993)85:3<287:PAPCOP>2.0.ZU;2-X
Abstract
The palladium catalyzed carbonylation of propargyl derivatives in the presence of phosphines and under phase transfer conditions leads to th e formation of allenic acids and olefinic diacids with good yields and very high selectivity.