Am. Plokhotnichenko et al., THE EFFECT OF ORIENTATIONAL DIFFUSION ON FORMATION OF PHENOL H-BONDEDCOMPLEXES IN AR MATRIX, Fizika nizkih temperatur, 19(9), 1993, pp. 1029-1033
The concentration dependence of IR spectra of phenol and diphenols in
the Ar matrix at T = 12 K is studied. The influence of sample annealin
g at 25-30 K on band intensities of isolated molecules and H-bonded ho
moassociates is considered. The effect of diffusion on the process of
complex formation is estimated, and a simple quantitative model is dev
eloped, permitting one lo evaluate a fraction of the H-bonded complexe
s of different conpositions in the sample with different concentration
s of the molecules of sufficiently high orientational mobility in the
matrix. The dimers are shown to predominate among the H-bonded complex
es of these molecules at a matrix dilution down to 1:100 due to the st
rong dependence of the orientational mobility of the complexes on thei
r sizes. Integral extinctions of the valence vibration bands of free a
nd H-bonded OH groups of phenols in the Ar matrix are calculated.