E. Nedkov et S. Tsvetkova, EFFECT OF GAMMA-IRRADIATION ON THE CRYSTALLINE-STRUCTURE OF ULTRA-HIGH-MOLECULAR-WEIGHT POLY(ETHYLENE OXIDE), Radiation physics and chemistry, 43(4), 1994, pp. 397-401
Citations number
20
Categorie Soggetti
Nuclear Sciences & Tecnology","Chemistry Physical","Physics, Atomic, Molecular & Chemical
To follow gamma-irradiation effect upon PEO crystalline structure WAXS
and SAXS investigations have been carried out. Thermal treated sample
s are prepared. Experimentally obtained data show that under irradiati
on with doses over 10 Mrad amorphous regions are mainly changed. Effec
t of radiation annealing and perfection of the crystalline structure i
s observed. Radiation with doses over 10 Mrad causes partial amorphiza
tion of crystallites and effect of radiation melting. A packing of the
lamellar aggregates and increasing of the porous size are observed.