The photocurrent and luminescence properties of thin (1 mum) YBa2Cu3O6
films on sapphire at 77 and 300 K are reported. We demonstrate that t
he luminescence mechanism of YBa2Cu3O6 depends considerably on the wav
elength of the excitation used. Completely different luminescence resp
onses are observed with the 351 and 458 nm lines. A fair agreement, li
ke that in semiconductors with band-to-band transitions, is found betw
een photocurrent and luminescence excited by the 458 nm line. The infl
uence of high electric fields (less-than-or-equal-to 5 780 V cm-1) on
the photocurrent and luminescence of YBa2Cu3O6 is investigated for the
first time. Similar effects on photon-induced tunneling phenomena (Fr
anz-Keldysh effect) are observed. However, we show that the observed e
ffects cannot be explained by photon-induced tunneling phenomena only
since the influence of an electric field on the band structure of YBa2
Cu3O6 is not only restricted to a bending of bands but modifies the ba
nd structure in a more complex manner.