Ls. Kotlyar et al., UNDERSTANDING OF FUNDAMENTALS - KEY TO PROCESS MODIFICATION FOR TAILINGS REDUCTION, Journal of environmental science and health. Part A: Environmental science and engineering, 28(10), 1993, pp. 2215-2224
The tailings produced during bitumen separation from oil sands have a
high water holding capacity attributed to ultrafine (less than or equa
l to to form gels in a matter of days. Gel formers are an integral par
t of oil sands ores which are unavoidably released during processing.
However, one way to prevent gel formation is to change the water chemi
stry in the extraction process where the bitumen is released. This can
be achieved by the addition of sodium silicate instead of sodium hydr
oxide as process aid in the initial oil sands conditioning step.0.2 mu
m), aluminosilicate clay fractions. These components readily form gel
s within which both fine and coarse particles may be embedded. This co
mplex mixture (or ''fine tails'') shows poor dewatering and consolidat
ion characteristics. In this work it has been demonstrated that for ge
l formation to occur an appropriate combination of ultrafines (amount
and particle size) and water chemistry is needed. The natural salt con
centration in water recycled from the tailings or pore (connate) water
is sufficient to cause the ultrafines to form gels in a matter of day
s. Gel formers are an integral part of oil sands ores which are unavoi
dably released during processing, However, one way to prevent gel form
ation is to change the water chemistry in the extraction process where
the bitumen is released. This can be achieved by the addition of sodi
um silicate instead of sodium hydroxide as process aid in the initial
oil sands conditioning step.