AZIDOCARBONYL-SUBSTITUTED CUBANOUREAS

Authors
GILARDI R GEORGE C KARLE J EATON PE RAO M
Citation
R. Gilardi et al., AZIDOCARBONYL-SUBSTITUTED CUBANOUREAS, Journal of heterocyclic chemistry, 30(5), 1993, pp. 1389-1391
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of heterocyclic chemistry → ACNP
ISSN journal
0022152X
Volume
30
Issue
5
Year of publication
1993
Pages
1389 - 1391
Database
ISI
SICI code
0022-152X(1993)30:5<1389:AC>2.0.ZU;2-F
Abstract
Despite the angular strain associated with the assembly of small rings , 1,2-diisocyanatocubane reacts with trimethylsilyl azide under mild c onditions to form a hexacyclic ring assembly that contains an imidazol idone ring fused to one edge of cubane. This compound was identified a s an azidocarbonyl-substituted cubanourea by means of X-ray crystal st ructure analysis of the nitro-derivative, the energetic compound N-azi docarbonyl-nitrocubanourea.