POLYMERIZATION BY PHASE-TRANSFER CATALYSIS .16. SYNTHESIS OF POLYESTERCARBONATES AND POLYESTERTHIOCARBONATES

Authors
TAGLE LH DIAZ FR CONCHA R CISTERNAS H
Citation
Lh. Tagle et al., POLYMERIZATION BY PHASE-TRANSFER CATALYSIS .16. SYNTHESIS OF POLYESTERCARBONATES AND POLYESTERTHIOCARBONATES, International journal of polymeric materials, 20(3-4), 1993, pp. 159-163
Citations number
17
Categorie Soggetti
Polymer Sciences","Engineering, Chemical
Journal title
International journal of polymeric materials → ACNP
ISSN journal
00914037
Volume
20
Issue
3-4
Year of publication
1993
Pages
159 - 163
Database
ISI
SICI code
0091-4037(1993)20:3-4<159:PBPC.S>2.0.ZU;2-1
Abstract
Polyestercarbonates and polyesterthiocarbonates were synthesized from the diphenol-esters 4-hydroxyphenyl-4-hydroxybenzoate and 3-hydroxyphe nyl-4-hydroxybenzoate and phosgene and thiophosgene respectively, unde r phase transfer catalysis conditions. The behaviour of the catalysts was evaluated by the yields and the inherent viscosities. Only the pol yesterthiocarbonate derived from 3-hydroxyphenyl-4-hydroxybenzoate was soluble in the reaction media, being benzyltriethylammonium chloride (TE-BAC) an effective catalyst for this synthesis.