MICHAEL REACTIONS WITH TRANS-3-ISOPROPENYL-2-PHENYLTHIOCYCLOPENTAN-1-ONE AND NS-3-ISOPROPENYL-2-PHENYLSULFONYLCYCLOPENTAN-1-ONE

Citation
Vv. Veselovsky et al., MICHAEL REACTIONS WITH TRANS-3-ISOPROPENYL-2-PHENYLTHIOCYCLOPENTAN-1-ONE AND NS-3-ISOPROPENYL-2-PHENYLSULFONYLCYCLOPENTAN-1-ONE, Russian chemical bulletin, 42(1), 1993, pp. 106-110
Citations number
7
Categorie Soggetti
Chemistry
Journal title
ISSN journal
10665285
Volume
42
Issue
1
Year of publication
1993
Pages
106 - 110
Database
ISI
SICI code
1066-5285(1993)42:1<106:MRWT>2.0.ZU;2-0
Abstract
The condensation of methyl acrylate with the title beta-ketosulfide an d beta-ketosulfone was studied. The primary adduct of beta-ketosulfone with acrolein readily undergoes intramolecular aldolization to give b icyclo[3.2.1]octane derivatives. The molecular structure of one of the m was elucidated by X-ray analysis.