VIBRATIONAL STUDIES OF MAGNESIUM HYDROGEN PHOSPHATE HYDROGEN AND BARIUM HYDROGEN PHOSPHATE CRYSTALS

Citation
P. Kolandaivel et al., VIBRATIONAL STUDIES OF MAGNESIUM HYDROGEN PHOSPHATE HYDROGEN AND BARIUM HYDROGEN PHOSPHATE CRYSTALS, Crystal research and technology, 28(8), 1993, pp. 1139-1145
Citations number
9
Categorie Soggetti
Crystallography
ISSN journal
02321300
Volume
28
Issue
8
Year of publication
1993
Pages
1139 - 1145
Database
ISI
SICI code
0232-1300(1993)28:8<1139:VSOMHP>2.0.ZU;2-#
Abstract
Magnesium hydrogen phosphate and Barium hydrogen phosphate crystals we re grown in the presence of sodium meta silicate (sol-gel method). Ram an and IR spectra were measured for the above crystals. Vibrational as signments were made for both the crystals. The large shift of the stre tching and bending modes of water from the free state values indicates the different hydrogen bonds strenghts present in the magnesium hydro gen phosphate crystals.