CATION-RADICAL MECHANISMS OF CATALYTIC HYDROCARBON CONVERSIONS - ISOMERIZATION OF ALKENES

Authors
VISHNETSKAYA MV ROMANOVSKII BV
Citation
Mv. Vishnetskaya et Bv. Romanovskii, CATION-RADICAL MECHANISMS OF CATALYTIC HYDROCARBON CONVERSIONS - ISOMERIZATION OF ALKENES, Petroleum chemistry, 33(4), 1993, pp. 299-302
Citations number
29
Categorie Soggetti
Energy & Fuels","Engineering, Chemical","Engineering, Petroleum
Journal title
Petroleum chemistry → ACNP
ISSN journal
09655441
Volume
33
Issue
4
Year of publication
1993
Pages
299 - 302
Database
ISI
SICI code
0965-5441(1993)33:4<299:CMOCHC>2.0.ZU;2-R
Abstract
An examination has been made of single-electron transfer from a substr ate molecule to the catalyst and the formation of a cation-radical as the first stage of alkene isomerization. Within the framework of this model, the stereospecificity of the reaction and the formation of cis- isomers as primary isomerization products are explained. as well as da ta on deuterated exchange.