Experimental observations are presented which indicate that porous sil
icon can be selectively converted to silicon dioxide. By presenting cr
oss-sectional transmission electron micrographs, nuclear analysis data
and electrical data, it is demonstrated that the selective oxidation
occurs when the surface of the porous silicon has been amorphized by i
on implantation. Electrical results are presented which show that the
oxide is of sufficient quality for isolation purposes. It is of note t
hat the partially oxidized porous silicon underlying the surface oxide
layer, which initially was constituted of very thin, vertical, silico
n 'wires', still exhibits a relatively low resistivity. The significan
ce of these observations for device fabrication is briefly discussed.