STEREOSELECTIVE SYNTHESIS OF TRANS-HYDROAZULENE DERIVATIVES BY TANDEMMICHAEL-INTRAMOLECULAR WITTIG REACTIONS OF A CYCLIC PHOSPHONIUM YLIDEWITH ALKYL OR ARYL 1-CYCLOPENTENYL KETONES

Authors
FUJIMOTO T UCHIYAMA YK KODAMA Y OHTA K YAMAMOTO I KAKEHI A
Citation
T. Fujimoto et al., STEREOSELECTIVE SYNTHESIS OF TRANS-HYDROAZULENE DERIVATIVES BY TANDEMMICHAEL-INTRAMOLECULAR WITTIG REACTIONS OF A CYCLIC PHOSPHONIUM YLIDEWITH ALKYL OR ARYL 1-CYCLOPENTENYL KETONES, Journal of organic chemistry, 58(26), 1993, pp. 7322-7323
Citations number
32
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of organic chemistry → ACNP
ISSN journal
00223263
Volume
58
Issue
26
Year of publication
1993
Pages
7322 - 7323
Database
ISI
SICI code
0022-3263(1993)58:26<7322:SSOTDB>2.0.ZU;2-3
Abstract
The reaction of 1-cyclopentenyl ketones 4a-c with 1,1-diphenylphosphol anium ylide 2 gave trans-hydroazulene derivatives 5a-c with high diast ereoselectivity via tandem Michael-intramolecular Wittig reactions.