DETERMINATION OF THE ENANTIOMERIC RATIO OF ORGANIC AMMONIUM HALIDES OR ALKALI CARBOXYLATES BY NMR-SPECTROSCOPY

Authors
BUDDRUS J HERZOG H RISCH K
Citation
J. Buddrus et al., DETERMINATION OF THE ENANTIOMERIC RATIO OF ORGANIC AMMONIUM HALIDES OR ALKALI CARBOXYLATES BY NMR-SPECTROSCOPY, Analytical chemistry, 66(1), 1994, pp. 40-42
Citations number
3
Categorie Soggetti
Chemistry Analytical
Journal title
Analytical chemistry → ACNP
ISSN journal
00032700
Volume
66
Issue
1
Year of publication
1994
Pages
40 - 42
Database
ISI
SICI code
0003-2700(1994)66:1<40:DOTERO>2.0.ZU;2-X
Abstract
The enantiomeric ratio of chiral ammonium halides or alkali carboxylat es can be determined by mixing the salt with an optically active carbo xylate or ammonium halide, respectively (eq 1), and investigating the diastereomeric associates by H-1- or C-13-NMR.