(CYCLOPENTADIENYL)-GALLIUM(I)-COMPOUNDS

Authors
LOOS D SCHNOCKEL H
Citation
D. Loos et H. Schnockel, (CYCLOPENTADIENYL)-GALLIUM(I)-COMPOUNDS, Journal of organometallic chemistry, 463(1-2), 1993, pp. 37-40
Citations number
31
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
463
Issue
1-2
Year of publication
1993
Pages
37 - 40
Database
ISI
SICI code
0022-328X(1993)463:1-2<37:(>2.0.ZU;2-1
Abstract
A metastable solution of GaCl reacts with LiCp or MgCp(2) compounds to a number of new cyclopentadienylgallium(I) species: GaCp, GaCp(tBu), GaCp((SiMe3)3) and GaCp((Benzyl)5). They are characterized by their m ass and NMR spectra (H-1, C-13 and Ga-71). By comparison with analogou s Al and Mg compounds eta(5)-bonding has to be concluded for air GaCp derivatives.